Diaqua­bis­(4-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ2N3,O4)manganese(II) N,N-dimethyl­formamide disolvate
2011

Study of a Manganese Complex with Imidazole Ligands

publication Evidence: moderate

Author Information

Author(s): Zhang Gang, Wang Yong

Primary Institution: Henan University of Urban Construction

Hypothesis

The study investigates the structure and properties of a manganese(II) complex formed with 2-ethyl-4,5-imidazoledicarboxylic acid.

Conclusion

The manganese(II) complex exhibits a distorted octahedral coordination environment and forms a two-dimensional polymeric structure through hydrogen bonding.

Supporting Evidence

  • The manganese(II) ion is hexa­coordinated by four O atoms and two N atoms.
  • The complex forms a two-dimensional polymeric structure through hydrogen bonds.
  • The study contributes to the understanding of coordination polymers based on imidazole carboxylate ligands.

Takeaway

Scientists created a special manganese compound using a specific acid, and it has a unique shape that helps it stick together with other molecules.

Methodology

The compound was synthesized by reacting manganese chloride with 2-ethyl-4,5-imidazoledicarboxylic acid in a DMF solution under hydrothermal conditions.

Digital Object Identifier (DOI)

10.1107/S1600536811020071

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