Metal-Organic Papers
2011

Structure of a Zinc Complex with Benzothiazole Ligands

publication Evidence: moderate

Author Information

Author(s): Sun Xue-Tong, Wang Xiu-Guang, Zhao Xiao-Jun

Primary Institution: Tianjin Normal University

Hypothesis

The study investigates the coordination behavior of benzothiazole ligands in metal complexes.

Conclusion

The zinc complex exhibits a slightly distorted tetrahedral coordination geometry and forms a one-dimensional supramolecular chain through hydrogen bonding.

Supporting Evidence

  • The zinc atom is coordinated by two nitrogen atoms from benzothiazole and two oxygen atoms from carboxylate ligands.
  • Hydrogen bonds link the mononuclear units into a one-dimensional chain.

Takeaway

The researchers created a zinc compound using special molecules and found that they stick together in a chain-like structure.

Methodology

The complex was synthesized from an ethanol solution of benzothiazole and 4-nitrobenzoic acid, followed by the addition of zinc chloride.

Digital Object Identifier (DOI)

10.1107/S1600536811022331

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