2,4-Dimethyl-N-(4-methylphenyl)benzene­sulfonamide
2011

Structure of 2,4-Dimethyl-N-(4-methylphenyl)benzenesulfonamide

publication Evidence: moderate

Author Information

Author(s): Nirmala P. G., Foro Sabine, Gowda B. Thimme

Primary Institution: Mangalore University

Hypothesis

The study investigates the structural effects of substituents on N-(aryl)arylsulfonamides.

Conclusion

The crystal structure of the compound shows two independent molecules with specific torsion angles and dihedral angles between the benzene rings.

Supporting Evidence

  • The asymmetric unit contains two independent molecules.
  • The molecules are twisted at the S—N bonds.
  • The dihedral angles between the benzene rings are 72.0° and 78.3°.

Takeaway

The researchers looked at how different groups attached to a molecule change its shape, and they found two similar but slightly different shapes in their crystals.

Methodology

The crystal structure was determined using X-ray diffraction techniques.

Digital Object Identifier (DOI)

10.1107/S1600536810049627

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