Poly[[(1,10-phenanthroline){μ3-2,2′,2′′-[1,3,5-triazine-2,4,6-triyltris(sulfanediyl)]triacetato}cadmium] 0.42-hydrate]
2011
New Cadmium Complex with Triazine Ligand
publication
Evidence: moderate
Author Information
Author(s): Chi Chun-Jing, Peng Yan-Qiang, Zeng Su-Yuan, Sun De-Zhi
Primary Institution: Liaocheng University, Shandong, People's Republic of China
Hypothesis
The study investigates the assembly of a new cadmium complex using a flexible triazine ligand.
Conclusion
The new cadmium complex exhibits a unique coordination geometry and forms two-dimensional supramolecular sheets.
Supporting Evidence
- The cadmium center is six-coordinated with a distorted octahedral geometry.
- Chains of cadmium complexes are formed through bridging ligands.
- Intermolecular interactions lead to the formation of two-dimensional sheets.
Takeaway
Scientists created a new compound using cadmium and a special molecule that helps it connect in interesting ways, forming sheets.
Methodology
The complex was synthesized by heating a mixture of cadmium acetate, triazine ligand, and phenanthroline in water.
Digital Object Identifier (DOI)
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