4-Bromobenzoyl 4-bromobenzoate monohydrate
2011
Crystal Structure of 4-Bromobenzoyl 4-bromobenzoate Monohydrate
publication
Evidence: moderate
Author Information
Author(s): Schmitt Bonell, Gerber Thomas, Hosten Eric, Betz Richard
Primary Institution: Nelson Mandela Metropolitan University
Conclusion
The study reveals the crystal structure of a hydrated anhydride of para-bromobenzoic acid, characterized by specific hydrogen bonding interactions.
Supporting Evidence
- The crystal structure shows a dihedral angle of 45.76° between the aromatic rings.
- Intermolecular hydrogen bonds link the molecules into chains parallel to the a axis.
- No π–π stacking interactions were observed in the crystal structure.
Takeaway
The researchers looked at a special chemical compound and found out how its tiny parts are arranged in a crystal, showing how they stick together.
Methodology
The compound was synthesized by reacting 4-bromobenzyl chloride with potassium thiocyanate and dipyridin-2-ylamine in refluxing acetone, followed by X-ray diffraction analysis.
Digital Object Identifier (DOI)
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