Diaqua­bis­(2-oxo-2H-chromene-3-carboxyl­ato)copper(II) [Cu(C10H5O4)2(H2O)2]
2011

Copper Complex with Coumarin-3-Carboxylic Acid

publication Evidence: moderate

Author Information

Author(s): Cui Yue, Gao Qian, Wang Huan-Huan, Wang Lin, Xie Ya-Bo

Primary Institution: Beijing University of Technology

Hypothesis

The study investigates the synthesis and crystal structure of a new mononuclear copper complex coordinated by coumarin-3-carboxylic acid.

Conclusion

The synthesized copper complex exhibits octahedral geometry and forms two-dimensional layers through hydrogen bonding.

Supporting Evidence

  • The copper atom in the complex is coordinated by two water molecules and two coumarin ligands.
  • The bond distances and angles around the copper atom are consistent with other known copper-oxygen complexes.
  • The complex forms layers through hydrogen bonding between water molecules and carboxylate groups.

Takeaway

Scientists made a new copper compound using a special acid, and it has a unique shape that helps it stick together in layers.

Methodology

The complex was synthesized by layering solutions of copper nitrate and coumarin-3-carboxylic acid, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811018708

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