Organic Papers
2011

Study of Butane-1,4-diaminium bis­[3,4,5,6-tetra­chloro-2-(meth­oxy­carbon­yl)benzoate]

publication

Author Information

Author(s): Liang Zu Pei

Primary Institution: Weifang University

Hypothesis

The reaction of 3,4,5,6-tetrachloro-2-(methoxycarbonyl)benzoic acid and butane-1,4-diamine in methanol was expected to yield a specific product.

Conclusion

The expected product was not obtained, and instead, a different compound was formed due to reduced reaction time and temperature.

Supporting Evidence

  • The cation lies on an inversion center.
  • The mean planes of meth­oxy­carbon­yl and carboxyl­ate groups form dihedral angles with the benzene ring.
  • Intermolecular N—H⋯O hydrogen bonds connect the components into sheets.

Takeaway

The researchers tried to make a specific chemical compound but ended up with something different because they didn't let it cook long enough.

Methodology

The reaction involved refluxing a mixture of 4,5,6,7-tetrachloroisobenzofuran-1,3-dione and methanol, followed by the addition of butane-1,4-diamine and natural evaporation to obtain crystals.

Limitations

The study did not achieve the intended product, which may limit the applicability of the findings.

Digital Object Identifier (DOI)

10.1107/S1600536811016795

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