Bis(tetraethylammonium) bis(dimethylformamide)tetrakis(μ-N,2-dioxidobenzene-1-carboximidato)pentacopper(II)
2011
Structure of a Copper Metallacrown Compound
publication
Evidence: moderate
Author Information
Author(s): Herring Jacob, Zeller Matthias, Zaleski Curtis M.
Primary Institution: Shippensburg University
Conclusion
The study presents the synthesis and detailed structural analysis of a copper metallacrown compound, revealing its unique coordination geometry and disorder characteristics.
Supporting Evidence
- The compound contains five CuII ions, with distinct coordination geometries.
- Static disorder is observed in the metallacrown and associated cations and solvent molecules.
- The study contributes to the understanding of metallacrown structures and their potential applications.
Takeaway
Scientists created a special copper compound that has a unique shape and arrangement of atoms, which can help in understanding how similar materials work.
Methodology
The compound was synthesized and analyzed using single-crystal X-ray diffraction.
Limitations
The structure shows severe static disorder, which may complicate the interpretation of the results.
Digital Object Identifier (DOI)
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