Organic Papers
2011

(3,5,5,6,8,8-Hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)methanol: a possible metabolite of the synthetic musk fragrance AHTN

publication Evidence: moderate

Author Information

Author(s): Faust Rüdiger, Nauroozi Djawed, Bruhn Clemens, Koch Britta, Kuhlich Paul, Piechotta Christian, Nehls Irene

Primary Institution: Institute for Chemistry, University of Kassel

Hypothesis

The study aims to elucidate the crystal structure of AHTN-OH to provide standard materials for the analysis of environmental pollutants.

Conclusion

The crystal structure of AHTN-OH was determined, revealing a tetra­meric cyclic motif formed by strong hydrogen bonds.

Supporting Evidence

  • The title compound was prepared to provide standard materials for analyzing environmental pollutants.
  • The structure determination was performed on racemic material, expressed in the structure as disordered chiral sites.
  • The asymmetric unit consists of four AHTN-OH molecules forming a tetra­meric cyclic motif.

Takeaway

The researchers studied a chemical compound related to a synthetic fragrance to understand its structure better, which can help in analyzing pollution.

Methodology

The compound was synthesized and its crystal structure was analyzed using X-ray diffraction.

Limitations

The study does not allow a correlation between the olfactoric qualities and the absolute configuration of the two enantiomers.

Digital Object Identifier (DOI)

10.1107/S1600536811018009

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