Bis[1,3-bis(2,4,6-trimethylphenyl)-2,3-dihydro-1H-imidazol-2-ylidene]dichloridodinitrosyltungsten(II) tetrahydrofuran-d8 monosolvate
2011
Study of a New Tungsten Compound
publication
Evidence: moderate
Author Information
Author(s): Fraga-Hernández Javier, Blacque Olivier, Berke Heinz
Primary Institution: University of Zürich
Hypothesis
The study investigates the molecular structure and properties of a new dinitrosyl tungsten complex.
Conclusion
The compound exhibits a distorted octahedral arrangement around the tungsten atom with specific bond angles and interactions.
Supporting Evidence
- The molecular structure shows a distorted octahedral arrangement around the tungsten atom.
- Bond angles deviate slightly from linearity, indicating structural distortion.
- Intermolecular interactions connect the organometallic molecule and solvent.
Takeaway
Scientists created a new tungsten compound and found that its structure is a bit twisted, which is interesting for chemistry.
Methodology
The compound was synthesized and characterized using various spectroscopic techniques and single-crystal X-ray diffraction.
Digital Object Identifier (DOI)
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