Organic Papers (Isopropylamino)(methyl)diphenylphosphonium iodide C16H21NP+·I−
2011
Synthesis of a New Organic Compound
publication
Evidence: low
Author Information
Author(s): Peulecke Normen, Peitz Stephan, Müller Bernd H., Spannenberg Anke, Rosenthal Uwe
Primary Institution: Leibniz-Institut für Katalyse e. V. an der Universität Rostock
Hypothesis
The reaction of a specific ligand with iodomethane will yield a phosphonium salt.
Conclusion
The expected phosphonium salt was not formed; instead, a new compound resulted from the cleavage of a PN bond.
Supporting Evidence
- The compound was characterized using standard analytical methods.
- A weak donor-acceptor interaction was observed in the structure.
- The synthesis involved a reaction in diethyl ether.
Takeaway
Scientists mixed two chemicals and expected one result, but they got something different that they didn't expect.
Methodology
The compound was synthesized by reacting a ligand with iodomethane in diethyl ether and then crystallized for analysis.
Digital Object Identifier (DOI)
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