X-ray absorption spectroscopy of FeH+ to aid its identification in astrochemical environments
2025

X-ray Absorption Spectroscopy of FeH+ for Astrochemical Identification

publication Evidence: moderate

Author Information

Author(s): Jin Shan, Flach Max, Ebenbichler Alexander, Cunningham Ethan M., Zamudio-Bayer Vicente, Hirsch Konstantin, van der Linde Christian, Przybilla Norbert, Ončák Milan, Lau J. Tobias, Beyer Martin K.

Primary Institution: Universität Innsbruck, Institut für Ionenphysik und Angewandte Physik

Hypothesis

Can the diatomic molecular ion FeH+ be identified in astronomical environments using X-ray absorption spectroscopy?

Conclusion

The study presents the first laboratory spectrum of FeH+ that can be compared with astronomical observations, suggesting its potential presence in the interstellar medium.

Supporting Evidence

  • This is the first laboratory spectrum of FeH+ suitable for comparison with astronomical data.
  • The study indicates that FeH+ cannot be ruled out as a component of the interstellar medium.
  • The iron 3d occupation in FeH+ was found to be 6.24, consistent with quantum chemical calculations.

Takeaway

Scientists took a special picture of a molecule called FeH+ to see if it exists in space, and they found it might be there!

Methodology

X-ray absorption spectroscopy was performed on FeH+ at the BESSY II facility, using an electrospray ionization source and a linear Paul trap.

Limitations

The study's findings are based on laboratory data that may not fully represent the complex conditions of the interstellar medium.

Digital Object Identifier (DOI)

10.1039/d4cc04702h

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