[μ2-Bis(diphenyl­phosphanyl)methane][μ3-bis­(diphenyl­phosphanyl)meth­yl]trichlorido­tetra­gold(I) tetra­hydro­furan disolvate [Au4(C25H21P2)Cl3(C25H22P2)]·2C4H8O
2011

New Tetranuclear Gold Complex with Bis(diphenylphosphanyl)methane

publication Evidence: moderate

Author Information

Author(s): Wang Huan-Huan, Gao Qian, Cui Yue, Wang Lin, Xie Ya-Bo

Primary Institution: Beijing University of Technology

Conclusion

The study presents a new tetranuclear gold complex with unique structural features.

Supporting Evidence

  • The compound features two non-equivalent phosphine fragments.
  • Each phosphorus atom is coordinated by a gold atom.
  • The structure includes two five-membered Au2P2C rings.

Takeaway

Scientists created a new gold compound that has a special shape and structure, which is different from what we usually see.

Methodology

The compound was synthesized by mixing gold chloride and bis(diphenylphosphanyl)methane in water and tetrahydrofuran, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536810054115

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