Characterizing Interactions Between Small Peptides and Dimethyl Sulfoxide Using Infrared Spectroscopy and Computational Methods
2024

Interactions Between Small Peptides and Dimethyl Sulfoxide

publication Evidence: moderate

Author Information

Author(s): Panuszko Aneta, Pastwa Przemysław, Gajewski Jacek, Bruździak Piotr

Primary Institution: Department of Physical Chemistry, Gdańsk University of Technology

Hypothesis

How does dimethyl sulfoxide (DMSO) interact with small peptides in aqueous solutions?

Conclusion

DMSO influences peptide stability differently based on their structural characteristics.

Supporting Evidence

  • DMSO does not form direct bonds with the peptides.
  • DMSO modifies the surrounding water molecules, influencing peptide stability.
  • The hydration shell of diglycine is strengthened by DMSO.
  • NAGMA's hydration shell is less affected by DMSO due to structural similarities.

Takeaway

This study looks at how a chemical called DMSO interacts with two small proteins in water, showing that it affects them in different ways.

Methodology

The study used FTIR spectroscopy and DFT calculations to analyze the interactions between DMSO and the peptides.

Digital Object Identifier (DOI)

10.3390/molecules29245869

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