catena-Poly[[(2,2′-bipyridine-κ2N,N′)cadmium]-μ3-4-nitro­phthalato-κ4O:O′,O′′:O′′′] [Cd(C8H3NO6)(C10H8N2)]
2011

Cadmium Coordination Polymer with 4-Nitrophthalate and 2,2'-Bipyridine

publication Evidence: moderate

Author Information

Author(s): Fan Yang, Xu Guo-Min, Lu Hai-Ting, Li Wei

Primary Institution: Xinyang Normal University

Hypothesis

The study aims to synthesize a coordination polymer using cadmium ions and 4-nitrophthalate ligands.

Conclusion

The synthesized coordination polymer exhibits a one-dimensional structure with cadmium ions linked by 4-nitrophthalate ligands.

Supporting Evidence

  • The coordination polymer exhibits a seven-membered chelate ring structure.
  • Weak hydrogen bonding is present in the crystal structure.
  • The compound shows good thermal stability up to 200 °C.

Takeaway

Scientists made a new material using cadmium and a special acid that helps connect the cadmium atoms in a chain.

Methodology

The compound was synthesized by mixing cadmium nitrate, 4-nitrophthalic acid, 2,2'-bipyridine, and sodium hydroxide in distilled water, followed by heating and cooling to obtain crystals.

Limitations

Only a few related coordination complexes and polymers have been reported, indicating limited prior research.

Digital Object Identifier (DOI)

10.1107/S1600536811000468

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