3-Amino-4-[4-(dimethyl­amino)­phen­yl]-4,5-dihydro-1,2,5-thia­diazole 1,1-dioxide
2011

Study of a Thiadiazole Compound

publication Evidence: moderate

Author Information

Author(s): Arslan N. Burcu, Ertürk Aliye Gediz, Kazak Canan, Bekdemir Yunus

Primary Institution: Ondokuz Mayıs University

Hypothesis

The study verifies the preference of the enamine-imine tautomeric form in the solid state.

Conclusion

The compound exists in the amine tautomeric form and forms hydrogen bonds in the crystal structure.

Supporting Evidence

  • The dihedral angle between the benzene and thiadiazolidine rings is 66.54°.
  • Molecules are linked by hydrogen bonds into a layer parallel to the ac plane.
  • The study confirms the existence of the compound in the amine tautomeric form.

Takeaway

This study looks at a specific chemical compound and how its molecules stick together in a solid form.

Methodology

The compound was synthesized using sodium cyanide and p-N,N-dimethyl benzaldehyde in a microwave.

Digital Object Identifier (DOI)

10.1107/S1600536811021520

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