Structure of a Metal-Organic Compound with Piperazine and Sulfanediyldiacetate
Author Information
Author(s): Ghadermazi Mohammad, Olmstead Marilyn M., Rostami Shahideh, Attar Gharamaleki Jafar
Primary Institution: Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran
Conclusion
The study presents the crystal structure of a complex involving cerium, piperazine, and sulfanediyldiacetate, revealing its polymeric nature and coordination environment.
Supporting Evidence
- The compound features a polymeric anion with a centrosymmetric Ce2O2 core.
- The study utilized X-ray diffraction to determine the crystal structure.
- The cerium cations are coordinated by sulfanediyldiacetate ligands in a distorted bicapped cubic environment.
Takeaway
Scientists studied a special compound made of metal and organic parts, showing how they are connected in a unique way.
Methodology
The compound was synthesized by mixing solutions of thiodiacetic acid and piperazine, followed by crystallization.
Limitations
The hydrogen atoms of the crystal water molecules could not be located and were not included in the refinement.
Digital Object Identifier (DOI)
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