Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ4 O,N,N′,O′}(formato-κO)manganese(III) dihydrate [Mn(C18H18N2O4)(CHO2)(H2O)]·2H2O
2011

Study of a Manganese(III) Complex with a Schiff Base Ligand

publication Evidence: moderate

Author Information

Author(s): Lee See Mun, Lo Kong Mun, Ng Seik Weng

Primary Institution: University of Malaya

Conclusion

The study reveals the formation of a three-dimensional network in the manganese(III) complex due to hydrogen bonding interactions.

Supporting Evidence

  • The manganese(III) atom is chelated by a Schiff base ligand.
  • Two metal-bearing molecules are linked by hydrogen bonds.
  • Adjacent dinuclear units form a three-dimensional network.

Takeaway

Scientists created a special manganese compound that forms a strong structure with water molecules, making it stable and interesting for further study.

Methodology

The manganese(III) complex was synthesized and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811017648

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