2-((Z)-{3-[(Z)-(2-Hy­droxy-5-methyl­benzyl­idene)amino]-2,2-dimethyl­prop­yl}imino­meth­yl)-4-methyl­phenol
2011

Crystal Structure of a Schiff Base Compound

publication Evidence: moderate

Author Information

Author(s): Kia Reza, Kargar Hadi, Mirkhani Valiollah, Ganji Fatemeh, Tahir Muhammad Nawaz

Primary Institution: Islamic Azad University, Tehran, Iran

Hypothesis

The study aims to determine the crystal structure of a tetradenate Schiff base ligand.

Conclusion

The title compound exhibits a skew geometry with strong intramolecular hydrogen bonds forming S(6) ring motifs.

Supporting Evidence

  • The dihedral angle between the two benzene rings is 73.47°.
  • Strong intramolecular O—H⋯N hydrogen bonds generate S(6) ring motifs.
  • The compound was synthesized by refluxing specific reactants in ethanol.

Takeaway

The researchers looked at a special chemical compound and found that its structure is twisted in a unique way, which helps it hold together better.

Methodology

The compound was synthesized and then analyzed using X-ray crystallography.

Limitations

The absolute structure could not be determined due to insufficient anomalous scattering.

Digital Object Identifier (DOI)

10.1107/S1600536810051688

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