Formaldehyde in Alcoholic Beverages: Large Chemical Survey Using Purpald Screening Followed by Chromotropic Acid Spectrophotometry with Multivariate Curve Resolution
2011

Formaldehyde in Alcoholic Beverages: A Large Chemical Survey

Sample size: 508 publication Evidence: moderate

Author Information

Author(s): Jendral Julien A., Monakhova Yulia B., Lachenmeier Dirk W.

Primary Institution: Chemisches und Veterinäruntersuchungsamt (CVUA) Karlsruhe

Hypothesis

Can a two-step method effectively analyze formaldehyde levels in alcoholic beverages?

Conclusion

The study confirmed that only 1.8% of the samples exceeded the WHO IPCS tolerable concentration for formaldehyde.

Supporting Evidence

  • 210 samples (41%) gave a positive purpald reaction.
  • 132 samples (26%) contained formaldehyde with an average of 0.27 mg/L.
  • The highest incidence of formaldehyde was found in tequila (83%) and Asian spirits (59%).
  • Only 9 samples (1.8%) had formaldehyde levels above the WHO IPCS tolerable concentration of 2.6 mg/L.

Takeaway

The researchers tested many alcoholic drinks to see how much formaldehyde they had, and found that most were safe.

Methodology

The study used a two-step method: a colorimetric test with purpald reagent followed by quantitative spectrophotometry using chromotropic acid.

Limitations

The purpald assay had a false positive rate of 37%, and the study did not conduct further validation in other matrices.

Digital Object Identifier (DOI)

10.1155/2011/797604

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