Metal-Organic Papers
2011
Two-dimensional polymeric mercury compound
publication
Evidence: moderate
Author Information
Author(s): Hameau Aurélien, Guyon Fabrice, Knorr Michael, Colquhoun Victoria P., Strohmann Carsten
Primary Institution: Institut UTINAM UMR CNRS 6213, Université de Franche-Comté
Hypothesis
The study investigates the synthesis and structure of a coordination polymer using the α,α-C4S6 dithione ligand.
Conclusion
The compound [Hg4I8(C4S6)]n is the first coordination polymer formed with the α,α-C4S6 ligand, exhibiting a two-dimensional structure.
Supporting Evidence
- The compound represents the first example of a coordination polymer assembled by the α,α-C4S6 dithione ligand.
- The HgII ions are four-coordinated in a distorted tetrahedral geometry.
- The coordination polymer has a two-dimensional structure built up of undulated layers.
Takeaway
Scientists made a new material using mercury and a special sulfur compound, and it has a unique layered structure.
Methodology
The α,α-C4S6 ligand was synthesized and reacted with HgI2 to form the coordination polymer, which was analyzed using X-ray crystallography.
Digital Object Identifier (DOI)
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