Metal-Organic Papers
2011
Study of a Cobalt(II) Complex with Azido Ligands
publication
Evidence: moderate
Author Information
Author(s): Phatchimkun Jaturong, Chaichit Narongsak
Primary Institution: Vongchavalitkul University
Hypothesis
The study investigates the crystal structure of a cobalt(II) complex with azido ligands and 5,5'-dimethyl-2,2'-bipyridyl.
Conclusion
The cobalt(II) ion in the complex adopts a distorted octahedral geometry stabilized by hydrogen bonds.
Supporting Evidence
- The cobalt(II) ion is coordinated by four nitrogen atoms from dmbpy and two azido nitrogen atoms.
- The crystal structure is stabilized by intramolecular and intermolecular hydrogen bonds.
- Only 16 crystal structures of cobalt(II) azido monomeric complexes have been reported.
Takeaway
The researchers looked at a special cobalt compound that has some nitrogen parts, and they found that it has a unique shape that helps it stay together.
Methodology
The compound was synthesized and characterized using X-ray crystallography.
Limitations
The study is limited to a single crystal structure and does not explore other potential complexes.
Digital Object Identifier (DOI)
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