Poly[[bis[μ-1,2-bis(4-pyridyl)ethene]bis(trichloroacetato)cadmium(II)] monohydrate]
2011
Crystal Structure of a Cadmium Complex with 1,2-bis(4-pyridyl)ethene
publication
Evidence: high
Author Information
Author(s): Kim Jin Hoon, Kim Cheal, Kim Youngmee
Primary Institution: Seoul National University of Science and Technology
Hypothesis
The study investigates the self-assembly of coordination polymers using cadmium ions and organic ligands.
Conclusion
The crystal structure reveals a two-dimensional network formed by cadmium ions and bridging ligands.
Supporting Evidence
- The cadmium ion is coordinated by two trichloroacetate ligands and two 1,2-bis(4-pyridyl)ethene ligands.
- The structure forms a three-dimensional network through hydrogen bonding.
- The crystal was refined to a high degree of accuracy with a low R-factor.
Takeaway
Scientists created a new crystal using cadmium and a special organic molecule, which connects in a unique way to form a structure.
Methodology
X-ray crystallography was used to determine the crystal structure of the compound.
Digital Object Identifier (DOI)
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