Organic Papers
2011
(Z)-4-(2,5-Di-tert-butylanilino)pent-3-en-2-one
publication
Author Information
Author(s): Jesús Pastrán, Andrea Ramírez, Giuseppe Agrifoglio, Anthony Linden, Romano Dorta
Primary Institution: Departamento de Química, Universidad Simón Bolívar, Caracas
Conclusion
The crystal structure of the compound shows an extensively delocalized π-system and a Z-configuration facilitated by an intramolecular hydrogen bond.
Supporting Evidence
- The molecule has a Z-configured alkene function.
- An intramolecular N—H⋯O hydrogen bond stabilizes the structure.
- The dihedral angle between the phenyl ring and alkene component is 63.45°.
Takeaway
The study looks at a special molecule that has a unique structure, which helps it stick together in a certain way.
Methodology
The compound was prepared by refluxing specific chemicals in ethanol and then crystallized.
Digital Object Identifier (DOI)
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