Diazido­{(S)-1-phenyl-N,N-bis­[(2-pyrid­yl)meth­yl]ethanamine}­copper(II) [Cu(N3)2(C20H21N3)]
2011

Copper Complex with a Chiral Ligand

publication Evidence: moderate

Author Information

Author(s): Rowthu Sankara Rao, Shin Jong Won, Kim Seung-Hui, Kim Jong Jin, Min Kil Sik

Primary Institution: Kyungpook National University

Hypothesis

The study investigates the synthesis and crystal structure of a five-coordinated CuII complex with a specific chiral ligand.

Conclusion

The copper complex exhibits a distorted square-pyramidal geometry and forms a one-dimensional chain structure through weak hydrogen bonding.

Supporting Evidence

  • The CuII ion is coordinated by three nitrogen atoms from the ligand and two azide anions.
  • The compound shows a distorted square-pyramidal geometry.
  • Weak hydrogen bonding interactions lead to a one-dimensional chain structure.

Takeaway

Scientists made a special copper compound that has a unique shape and can connect with other molecules in a chain-like way.

Methodology

The compound was synthesized using a mixture of solvents and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811021234

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