Enhancement of Thermochemical Energy Storage by Alkali Metal Chloride Salts-Doped Ca-Based Sorbents: A Combined DFT and Experimental Study
2024

Improving Energy Storage with Salt-Doped Calcium Materials

publication Evidence: high

Author Information

Author(s): Kong Dehao, He Nan, Chen Qicheng, Nie Binjian, Zhang Yingjin, An Nan, Yao Liang, Wang Zhihui

Primary Institution: Northeast Electric Power University

Hypothesis

Doping calcium-based sorbents with alkali metal chloride salts enhances thermochemical energy storage performance.

Conclusion

Doping with NaCl and KCl significantly increases the reaction rate and cycle stability of calcium-based materials for energy storage.

Supporting Evidence

  • Doping with NaCl and KCl improved the effective conversion rates of calcium-based materials.
  • The KCl-CaO composites showed the best performance in energy storage.
  • NaCl and KCl doping increased the surface area and delayed sintering of the materials.

Takeaway

Adding salt to calcium materials helps them store energy better and work longer without breaking down.

Methodology

The study used experiments and DFT calculations to analyze the effects of NaCl and KCl on calcium-based materials.

Digital Object Identifier (DOI)

10.3390/molecules29246058

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