Metal-Organic Papers(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis[O,O′-bis(4-methylphenyl) thiophosphate]
2011
Structure of a Nickel Complex with a Macrocyclic Ligand
publication
Evidence: moderate
Author Information
Author(s): Xiang Yang-Guang, Xie Bin, Zou Li-Ke, Feng Jian-Shen, Lai Chuan
Primary Institution: Sichuan University of Science and Engineering
Conclusion
The study presents the crystal structure of a nickel complex with a macrocyclic ligand, revealing its coordination geometry and hydrogen bonding interactions.
Supporting Evidence
- The nickel ion is coordinated by four nitrogen atoms and two oxygen atoms.
- The complex exhibits a slightly distorted octahedral geometry.
- Intramolecular hydrogen bonding is observed between the ligand and the anion.
Takeaway
The researchers made a special nickel compound that has a unique shape and bonds in a specific way, which helps us understand how these types of compounds work.
Methodology
The compound was synthesized and characterized using X-ray crystallography.
Digital Object Identifier (DOI)
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