High‐Entropy PdRhFeCoMo Metallene With High C1 Selectivity and Anti‐Poisoning Ability for Ethanol Electrooxidation
2024

High-Entropy PdRhFeCoMo Metallene for Ethanol Electrooxidation

publication Evidence: high

Author Information

Author(s): Tan Xiaohong, Wang Chenhui, Wang Jiarui, Wang Peng, Xiao Yuhang, Guo Yingying, Chen Jianpo, He Weidong, Li Yan, Cui Hao, Wang Chengxin

Primary Institution: School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, China

Hypothesis

Can a novel high-entropy metallene catalyst improve the efficiency of ethanol oxidation reactions?

Conclusion

The high-entropy PdRhFeCoMo metallene exhibits excellent performance in ethanol oxidation with high C1 selectivity and resistance to poisoning.

Supporting Evidence

  • The PdRhFeCoMo HEM shows a mass activity of 7.47 A mgPd+Rh −1.
  • It retains a mass activity of 0.56 A mgPd+Rh −1 after 20,000 seconds of testing.
  • The C1 selectivity of the catalyst reaches up to 84.12%.
  • The flexible solid-state ethanol fuel cell demonstrates a maximum power density of 20.1 mW cm−2.

Takeaway

Scientists created a new type of catalyst that helps turn ethanol into energy more efficiently and doesn't get easily damaged.

Methodology

A two-dimensional high-entropy metallene was synthesized using a mild one-step solvothermal method.

Digital Object Identifier (DOI)

10.1002/advs.202409109

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