Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate
2011
Copper(II) Complex with Pyridine and Dicyanamide
publication
Evidence: moderate
Author Information
Author(s): Wöhlert Susanne, Wriedt Mario, Jess Inke, Näther Christian
Primary Institution: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel
Hypothesis
New transition metal dicyanamides can be prepared using copper(II) chloride, sodium dicyanamide, and pyridine.
Conclusion
The study successfully characterized a new copper(II) complex with a unique crystal structure.
Supporting Evidence
- The copper(II) cation is coordinated by one chloride anion and four pyridine ligands.
- The crystal structure shows a square-pyramidal coordination environment.
- An additional chloride anion leads to a distorted octahedral coordination mode.
Takeaway
Scientists made a new type of copper compound by mixing some chemicals, and they found it has a special shape.
Methodology
Single crystal X-ray diffraction was used to characterize the crystal structure.
Limitations
The crystal investigated was racemically twinned, which may affect the results.
Digital Object Identifier (DOI)
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