Diaqua(2,2′-bipyridine-κ2N,N′)bis(perchlorato-κO)copper(II) [Cu(ClO4)2(C10H8N2)(H2O)2]
2011
Copper(II) Complex with 2,2'-Bipyridine
publication
Evidence: moderate
Author Information
Author(s): Damous Maamar, Hamlaoui Meriem, Bouacida Sofiane, Merazig Hocine, Daran Jean-Claude
Primary Institution: Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Université Mentouri-Constantine, Algeria
Conclusion
The study presents a copper(II) complex that exhibits a Jahn-Teller distorted octahedral geometry and is stabilized by hydrogen bonds and stacking interactions.
Supporting Evidence
- The copper(II) complex shows a Jahn-Teller distortion.
- The structure is stabilized by hydrogen bonds and π–π stacking interactions.
- The crystal packing consists of alternating layers of polyhedrals.
Takeaway
Scientists created a special copper compound that has a unique shape and sticks together in layers, which helps it stay stable.
Methodology
The compound was synthesized by mixing copper(II) acetate monohydrate with 2,2'-bipyridine and perchloric acid in methanol, followed by crystallization.
Digital Object Identifier (DOI)
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