Chloridobis(1,10-phenanthroline-κ2N,N′)copper(I) dichloridocopper(II) [CuCl(C12H8N2)2]·[CuCl2]
2011
Copper Complex with 1,10-Phenanthroline
publication
Evidence: moderate
Author Information
Author(s): Meng Qingfen, Chen Yanmei, Li Bing, Chen Sanping, Gao Shengli
Primary Institution: Northwest University
Hypothesis
The study investigates a mixed-charge copper complex using 1,10-phenanthroline as a ligand.
Conclusion
The synthesized copper complex exhibits a unique sandwich-like structure formed through π-π interactions.
Supporting Evidence
- The complex contains two Cu(II) cations and two cuprate(I) anions.
- The Cu(II) atom is coordinated by two phenanthroline molecules and one chloride anion.
- The structure features π-π stacking with an interplanar distance of 3.481 Å.
Takeaway
Scientists made a special copper compound using a chemical called 1,10-phenanthroline, and it has a cool layered structure.
Methodology
The complex was synthesized through a solvothermal reaction involving specific amounts of 1,10-phenanthroline, CuCl2.2H2O, and another ligand in ethanol.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website