Bis[2-(cyclo­pentyl­imino­meth­yl)-4-nitro­phenolato-κ2N2,O]cobalt(II)
2011

Cobalt(II) Complex with Schiff Base Ligands

publication Evidence: moderate

Author Information

Author(s): Xu Mai, Wei Yi-Jun, Wang Feng-Wu

Primary Institution: Huainan Normal College

Conclusion

The study reports the structure of a cobalt(II) complex with Schiff base ligands, revealing a distorted tetrahedral geometry.

Supporting Evidence

  • The cobalt(II) ion is coordinated by two N and two O atoms from two Schiff base ligands.
  • The cyclopentyl ring in the ligand is disordered over two conformations.
  • The study provides crystallographic data for the cobalt complex.

Takeaway

Scientists made a special cobalt compound using two types of molecules that help it hold onto metal. They found that the shape of the compound is a bit squished.

Methodology

The complex was synthesized by stirring specific amounts of 5-nitrosalicylaldehyde, cyclopentylamine, and cobalt(II) acetate in methanol, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811002194

Want to read the original?

Access the complete publication on the publisher's website

View Original Publication