catena-Poly[bis[(1,10-phenanthroline)cobalt(II)]-μ4-3,6-dicarboxycyclohexane-1,2,4,5-tetracarboxylato] [Co2(C12H8O12)(C12H8N2)2]
2011
New Cobalt Coordination Polymer with Flexible Ligands
publication
Evidence: moderate
Author Information
Author(s): Xu Wei
Primary Institution: Ningbo University
Hypothesis
The study investigates the synthesis and structural properties of a new cobalt coordination polymer using a flexible cycloalkane polycarboxylic acid ligand.
Conclusion
The new cobalt coordination polymer exhibits a three-dimensional network structure formed through hydrogen bonding and π-π stacking interactions.
Supporting Evidence
- The cobalt coordination polymer was formed under hydrothermal conditions.
- The structure features polymeric chains running along the [010] direction.
- The coordination around cobalt atoms is octahedral and significantly distorted.
Takeaway
Scientists created a new type of cobalt compound that has a special structure, which could be useful for future applications.
Methodology
The compound was synthesized through a hydrothermal reaction of Co2+ cations, phen, and H6chhc.
Digital Object Identifier (DOI)
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