Tetra­methyl­ammonium hemi(terephthalate) dihydrate
2011

Tetra­methyl­ammonium hemi(terephthalate) dihydrate

publication Evidence: moderate

Author Information

Author(s): Yang Yunxia, Shi Laipeng

Primary Institution: Northwest Normal University

Conclusion

The study presents the crystal structure of a compound formed by tetra­methyl­ammonium and terephthalate ions, revealing a unique sandwich-like arrangement.

Supporting Evidence

  • The crystal structure features a dihedral angle of 23.5° between the carboxylate group and its parent ring.
  • Two independent water molecules act as both donors and acceptors in the hydrogen-bonded host layers.
  • The tetra­methyl­ammonium cations are arranged in two rows between the host layers.

Takeaway

Scientists created a special crystal using certain chemicals, and it looks like a sandwich with layers.

Methodology

The compound was synthesized by dissolving biphenyl-4,4'-dicarboxylic acid in a water-ethanol mixture and adding tetramethylammonium hydroxide.

Digital Object Identifier (DOI)

10.1107/S1600536811023312

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