Acetonitrile­dicarbon­yl(η5-penta­methyl­cyclo­penta­dien­yl)iron(II) tetra­fluorido­borate [Fe(C10H15)(C2H3N)(CO)2]BF4
2011

Structure of a Metal-Organic Compound

publication Evidence: moderate

Author Information

Author(s): M'thiruaine Cyprian M., Friedrich Holger B., Changamu Evans O., Bala Muhammad D.

Primary Institution: University of KwaZulu-Natal

Conclusion

The compound crystallizes in a pseudo-octahedral arrangement around the iron atom.

Supporting Evidence

  • The compound was obtained as a yellow microcrystalline solid with a yield of 92%.
  • The arrangement of ligands around the iron atom is in a pseudo-octahedral three-legged piano-stool fashion.
  • The Fe—N bond length was measured at 1.924 Å.

Takeaway

Scientists studied a special metal compound and found out how its parts are arranged around the metal atom.

Methodology

The compound was synthesized using a known method and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811021350

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