Metal-Organic Papers
2011

Crystal Structure of a Zinc Complex with a Diamine Ligand

publication Evidence: high

Author Information

Author(s): Bortoluzzi Adailton J., Mireski Sandro L., Joussef Antonio C.

Primary Institution: Depto. de Química – UFSC, Florianópolis, SC, Brazil

Conclusion

The study successfully determined the crystal structure of a new zinc complex, revealing its unique coordination geometry and hydrogen bonding interactions.

Supporting Evidence

  • The zinc complex was isolated from a mixture of stereo isomeric diamines.
  • The coordination geometry of the zinc ion is approximately square-pyramidal.
  • Hydrogen bonds form dimeric structures in the crystal.

Takeaway

Scientists figured out how a new zinc compound is structured, showing how the zinc is surrounded by special molecules and how they stick together.

Methodology

The compound was synthesized by mixing a diamine ligand with zinc chloride in methanol, followed by crystallization and X-ray crystallographic analysis.

Digital Object Identifier (DOI)

10.1107/S1600536811004314

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