Bis{μ-2-[(pyridin-2-yl)imino­meth­yl]phenolato}bis­[(2-formyl­phenolato)copper(II)] [Cu2(C12H9N2O)2(C7H5O2)2]
2011

Copper Complex with Pyridine and Salicylaldehyde Ligands

publication Evidence: high

Author Information

Author(s): Chang Hui-Chang, Cole Jacqueline M., Lin Tze-Chia, Sylvester Sven O., Waddell Paul G.

Primary Institution: Cavendish Laboratory, University of Cambridge

Conclusion

The study reveals the formation of dimers in a copper complex due to specific intermolecular interactions.

Supporting Evidence

  • The compound forms dimers through interactions between copper and nitrogen atoms.
  • The geometry of copper changes from square-planar to square-based pyramidal in the dimer.
  • Bond lengths in the compound are compared to known polymorphs of similar copper complexes.

Takeaway

Scientists created a special copper compound that sticks together in pairs, and they figured out how it looks and behaves.

Methodology

Single-crystal X-ray crystallography was used to determine the structure of the compound.

Digital Object Identifier (DOI)

10.1107/S1600536811015674

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