Poly[[hexaaquabis(μ3-benzene-1,3,5-tricarboxylato-κ3O1:O3:O5)bis(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)trizinc] hexahydrate] [Zn3(C9H3O6)2(C12H12N2)2(H2O)6]·6H2O
2011
Study of a Zinc Complex with Benzene-1,3,5-Tricarboxylic Acid
publication
Evidence: moderate
Author Information
Author(s): Shan Wen-Wen, Xiong Han-Lin, Mei Chong-Zhen
Primary Institution: North China University of Water Conservancy and Electric Power
Hypothesis
The study aims to explore the influence of multicarboxylates and N-donor ligands on the properties and construction of coordination compounds.
Conclusion
The synthesized zinc complex exhibits a one-dimensional ladder structure and forms a three-dimensional supramolecular structure through hydrogen bonds and π–π interactions.
Supporting Evidence
- The compound features a one-dimensional ladder structure.
- Hydrogen bonds and π–π interactions contribute to the three-dimensional structure.
- The synthesis yielded colorless block crystals in 72% yield based on zinc.
Takeaway
The researchers made a special zinc compound that has a unique structure, which could be useful for making new materials.
Methodology
The compound was synthesized hydrothermally using a mixture of specific reagents at high temperature.
Digital Object Identifier (DOI)
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