Metal-Organic Papers
2011

Copper(II) Complex with Schiff Base Ligand

publication Evidence: moderate

Author Information

Author(s): Pu Xuewei, Li Lianzhi, Dong Jianfang, Jing Buqin

Primary Institution: Liaocheng University

Hypothesis

The study investigates the synthesis and crystal structure of a new copper(II) complex with a tridentate Schiff base ligand.

Conclusion

The copper(II) complex exhibits a distorted square-pyramidal geometry and forms a two-dimensional network through hydrogen bonding.

Supporting Evidence

  • The central CuII ion is five-coordinate, bound to one N atom and two O atoms from the Schiff base ligand.
  • The complex forms a distorted square-pyramidal configuration.
  • Intermolecular hydrogen bonds create a two-dimensional network in the crystal.

Takeaway

Scientists made a new copper compound using a special ingredient from plants, and they found that it has a unique shape and structure.

Methodology

The compound was synthesized by mixing L-tyrosine and o-vanillin in methanol, followed by the addition of cupric acetate and 1,10-phenanthroline.

Digital Object Identifier (DOI)

10.1107/S1600536811009627

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