Effect of Chemical Structure and Apparent Density of Rigid Polyurethane Foams on the Properties of Their Chemical Recycling Products
2024

Properties of Rigid Polyurethane Foams and Their Recycling Products

publication 10 minutes Evidence: moderate

Author Information

Author(s): Zemła Marcin, Kurańska Maria, Vevere Laima, Kirpluks Mikelis, Malewska Elżbieta, Apostolou Maria Sofia, Prociak Aleksander

Primary Institution: Faculty of Chemical Engineering and Technology, Cracow University of Technology

Hypothesis

The type of biopolyol used in polyurethane foam systems significantly impacts the properties of the resulting glycolyzed products.

Conclusion

The study found that petroleum-based foams exhibited better mechanical properties and lower thermal conductivity compared to bio-based foams, while the glycolyzed products from biopolyols showed higher reactivity.

Supporting Evidence

  • Petroleum-based foams had compressive strength ranging from 241 to 1323 kPa.
  • Bio-based foams had a closed cell content ranging from 15.9% to 53.9%.
  • Thermal conductivity of bio-based foams was significantly higher, ranging from 37.01 to 42.30 mW/m·K.

Takeaway

This study looked at different types of foam made from oil and plants, and how they can be recycled. The oil-based foam was stronger, but the plant-based foam was easier to recycle.

Methodology

The study synthesized polyurethane foams from petrochemical and biopolyols, tested their properties, and analyzed the glycolysis products using diethylene glycol.

Limitations

The study did not explore the long-term environmental impacts of using recycled materials.

Digital Object Identifier (DOI)

10.3390/ma17246190

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