Di-μ-chlorido-bis{chlorido[4-nitro-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)} [Hg2Cl4(C12H9N3O2)2]
2011
Crystal Structure of a Mercury(II) Complex
publication
Evidence: moderate
Author Information
Author(s): Salehzadeh Sadegh, Dehghanpour Saeed, Khalaj Mehdi, Rahimishakiba Mohammad
Primary Institution: Bu-Ali Sina University
Hypothesis
The study investigates the crystal structure of a specific mercury(II) complex with diimine ligands.
Conclusion
The crystal structure reveals a distorted square-pyramidal coordination environment around the mercury ion.
Supporting Evidence
- The mercury ion is in a distorted square-pyramidal coordination environment.
- The complex was prepared with a yield of 60%.
- Data collection was performed using a Nonius KappaCCD diffractometer.
Takeaway
Scientists made a special mercury compound and looked at its structure using X-rays. They found that the mercury is surrounded by certain atoms in a unique shape.
Methodology
The complex was synthesized from the reaction of HgCl2 and a diimine ligand, followed by crystallization.
Digital Object Identifier (DOI)
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