Bis(8-hydroxy-2-methylquinolinium) bis(pyridine-2,6-dicarboxylato)nickelate(II) methanol monosolvate monohydrate
2011
Study of a Nickel Complex with Hydroxyquinoline and Dicarboxylate Ligands
publication
Evidence: moderate
Author Information
Author(s): Aghabozorg Hossein, Gholizadeh Ahmad, Mirzaei Masoud, Notash Behrouz, Moshki Niloofar
Primary Institution: Faculty of Chemistry, Islamic Azad University, North Tehran Branch, Tehran, Iran
Conclusion
The study presents a nickel complex with a distorted octahedral geometry stabilized by various noncovalent interactions.
Supporting Evidence
- The nickel atom in the compound is coordinated by two dicarboxylate ligands.
- The geometry of the nickel complex is described as distorted octahedral.
- Noncovalent interactions, including hydrogen bonds and π–π stacking, stabilize the crystal structure.
Takeaway
Scientists created a special nickel compound that has a unique shape and is held together by different types of bonds, making it stable.
Methodology
The compound was synthesized by mixing 8-hydroxy-2-methylquinoline, pyridine-2,6-dicarboxylic acid, and nickel nitrate in methanol, followed by slow evaporation to obtain crystals for X-ray analysis.
Digital Object Identifier (DOI)
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