1,6-Bis(chloro­meth­yl)pyridine
2011

Crystal Structure of 1,6-Bis(chloromethyl)pyridine

publication Evidence: moderate

Author Information

Author(s): Richard Betz, Thomas Gerber, Henk Schalekamp

Primary Institution: Nelson Mandela Metropolitan University

Hypothesis

The study aims to determine the crystal structure of a halogenated derivative of 2,6-lutidine.

Conclusion

The crystal structure reveals that the chloromethyl groups are oriented on opposite sides of the aromatic plane, forming weak Cl⋯Cl contacts.

Supporting Evidence

  • The chloromethyl substituents are positioned on opposite sides of the aromatic plane.
  • Weak dispersive Cl⋯Cl contacts connect the molecules into chains.
  • A π–π interaction was observed with a centroid–centroid distance of 3.7481 Å.

Takeaway

Scientists looked at how a special chemical compound is arranged in 3D space, and they found that some parts of it stick out in different directions.

Methodology

X-ray diffraction was used to determine the crystal structure.

Digital Object Identifier (DOI)

10.1107/S1600536811020678

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